Molybdenum pentachloride (MoCl5) is demonstrated as a promising cathode for all-solid-state lithium batteries. Reversible lithiation is enabled by an electrochemically driven coordination rearrangeme...

Low-energy photons from deep-red (DR) to near-infrared (NIR) light offer unique opportunities for sustainable photochemical synthesis but suffer from intrinsically limited reactivity. This Review sum...

In Research Article (e5126293), Ashot V. Arzumanyan and co-workers propose recyclable Pt-catalyzed biphase hydrosilylation. The method allows preparing Pt-free monomeric and polymeric products isolat...

Stabilization of elusive aluminum(I) halides in the framework of an ambiphilic ligand is reported. The unique bonding situation at the trigonal-bipyramidal aluminum center is analyzed, and the coordi....

Spontaneously aligned, long-range hexagonal columnar ordering is obtained in phase-separated dynamic covalent networks by combining discrete siloxanes and dynamic acylsemicarbazide bonds. The ordered...

The first Pu(VI) plutonyl cage cluster, {Pu60}, forms a 2.5-nm metal-oxide cage with a unique distorted truncated dodecahedral topology. This discovery expands aqueous plutonium chemistry and opens n...

Three states, four inputs: a diborylated dihydrophenazine (BNNB) links aromaticity changes to B─N bond rotations, giving bent, intermediate, and planar conformations. Heat, force, light, or redox cha...

Maxson and Szilvási use a machine-learned interatomic potential to model supported silver nanoparticles. They show that the idealized nanoparticle shapes commonly invoked in the computational catalys...

Methods to access 1,3-functionalized patterns from alkenes remain limited. Recently, Silvi and co-workers reported a strategy to add the methyl thianthrenium radical across alkenes to rapidly produce....

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This highlight underscores the most straightforward synthesis of [2]catenanes from readily available molecular precursors: The one-pot, two-step catenane formation from a crown ether, a linear diamin...

Interactions between guanidinium cations and para-mercaptobenzoic acid ligands on Au nanoclusters trigger ligand reorganization and open new mass transport channels. These effects facilitate access o...

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