Spontaneously aligned, long-range hexagonal columnar ordering is obtained in phase-separated dynamic covalent networks by combining discrete siloxanes and dynamic acylsemicarbazide bonds. The ordered...

Proton‑transfer catalysis controls acylsemicarbazide dissociation, linking proton affinity to exchange kinetics and enabling predictive design of robust, tunable dynamic covalent networks.

Inspired by nature's dynamic materials, we here develop photoresponsive single-chain polymeric nanoparticles (SCPNs) that undergo light-induced changes in their polymeric microenvironment while retain...

A novel [(NHC)2Cu]Br (Cu(i)–NHC) complex promotes CuAAC reactions in organic solvents, water, buffers and even complex biological media in good yields. Encapsulation of the Cu catalyst in an amphiphilic...

A novel [(NHC)2Cu]Br (Cu(I)-NHC) complex promotes CuAAC reactions in organic solvents, water, buffers and even in complex biological media in good yields. Encapsulation of the Cu catalyst in an amphip...

Predicting 3D structures of synthetic heterograft polymers in solution starting from a chemical structure remains a great challenge. Here, we get grip on the 3D structures formed by amphiphilic, rando...