L’une des plus coûteuses et fraudogènes niches fiscales à destination des entreprises pourrait être revue par le gouvernement, suscitant des cris d’orfraie du patronat. ...

Nature Chemistry, Published online: 21 July 2026; doi:10.1038/s41557-026-02152-3Metal-stabilized nitrenes are important intermediates in nitrogen-atom transfer chemistry, but their isolation is challenging. Now a formal gold(III) aura-nitrene with triplet diradical character has been generated through photoirradiation of an azide precursor. The resulting nitrene enables a range of reactions, including O2 activation and C–H functionalization.

A Surface OrganoMetallic Chemistry (SOMC) approach, leveraging a molecularly defined heterobimetallic niobium–iridium complex, was used to prepare a mesoporous SBA-15 silica-supported Ir-NbOx catalyst...

This work demonstrates the synthesis of cationic Pt(II) η3-cycloallyl complexes, and experimental and computational studies show a ligand bite-angle dependence of their formation rates. The reactivit...

TRIBUNE. Le désengagement de l’Etat, qui vient d’annoncer une réduction du budget du CNRS de 20 millions d’euros pour l’année en cours, de la recherche publique aura des effets néfastes à long terme p...

While late 3d metals dominate efforts to replace precious metals in homogeneous hydrogenation, molybdenum has remained largely ignored. This work reveals that a nine-coordinate pentahydrido molybdenu...

Organic radicals play pivotal roles in chemistry, biology, and materials science. Although typically short-lived and highly reactive, considerable efforts have been devoted to stabilizing open-shell m...

Heterobimetallic compounds offer unique opportunities for activating substrates through cooperative interactions between two distinct metal centers, potentially leading to catalytic reactivity beyond ...

A frustrated redox triad comprising Al(C6F5)3 (AlCF), CO2, and decamethylferrocene (FeCp*2) promotes reductive disproportionation of CO2 to CO and carbonate under ambient conditions. Spectroscopic and computational data show that a Lewis acid-bound CO2 ...

Please note that job descriptions are not exhaustive, and you may be asked to take on additional duties that align with the key responsibilities ment...

PhD Project - PhD in Chemistry: Single or Double? A Radical Approach to Catalysis - Competitive EPSRC funded post at Cardiff University, listed on FindAPhD.com

Organic radicals play pivotal roles across chemistry, biology, and materials science. Although typically short-lived and highly reactive, considerable efforts have been devoted to stabilizing open-she...

Protonation of a heterometallic silanide complex with an alcohol led to formation of a σ-silane complex. This reaction does not require a strong acid or weakly coordinating anion. Both metals of the h...

From January 1st 2026, the CNRS will cut access to one of the largest commercial bibliometric databases, Clarivate Analytics'

The cationic nine-coordinate pentahydrido complex [MoH5(depe)2]BPh4 (1·BPh4, depe = 1,2-(diethylphosphino)ethane) is, to the best of our knowledge, the first early transition metal polyhydride shown t...