Reposted by Olivier Baslé
Thrilled to share my first corresponding author paper with my PhD supervisors S.Bontemps (@lcc-smac.bsky.social), @obasle.bsky.social and A.Lledos! We report a new air- and water-persistent C-centered radical anion via Frustrated Lewis Pair (FLP) activation of CO2. (doi.org/10.1021/jacs...)
doi.org
Air- and Water-Persistent C-Centered Radical Anion Based on FLP-Type-Activated CO2
Organic radicals play pivotal roles in chemistry, biology, and materials science. Although typically short-lived and highly reactive, considerable efforts have been devoted to stabilizing open-shell m...