The unique photophysical properties of heavy T-shaped Sb and Bi trisamides are reported. A ligand-to-pnictogen charge-transfer excitation from a redox-active NNN pincer to a vacant pnictogen p-orbita...

Im Jahr 2025 waren aller guten Dinge der Hauptgruppenchemie drei: ein dreifach geladenes Triborattrianion, ein Molekül mit linearer Al3-Einheit, das dritte Erdalkalimetall, das Stickstoff bindet, ein ...

Im Jahr 2025 waren aller guten Dinge der Hauptgruppenchemie drei: ein dreifach geladenes Triborattrianion, ein Molekül mit linearer Al3-Einheit, das dritte Erdalkalimetall, das Stickstoff bindet, ein ...

We report the transition-metal-like reactivity of a geometrically constrained, ambiphilic bismuth(III) trisamide. Planarization of the Bi(III) center unlocks Bi–C bond formation when reacted with mild...

The influence of various p-block element motifs on the photophysical properties of conjugated inorganic-organic hybrid polymers is surveyed regarding applications in organic electronics. Recent advan...

PhD Project - Sustainable Catalysis with Sb and Bi Pincer Complexes at The University of Manchester, listed on FindAPhD.com

PhD Project - PhD Studentship in C–H Functionalisation Using Polymetallic Complexes at Imperial College London, listed on FindAPhD.com

Nitrene insertion into the Ge<span class='icomoon'></span>Si bonds of masked bis(germylene)s is followed by nitrene addition to the Ge(II) centers to provide a bis(germaamidine) with GeN bonds bridged via a σ,π-conjugated amin...

The oxidation of triphenylphosphine by perfluorinated phenaziniumF aluminate in difluorobenzene affords hexaaryl-1,2-diphosphonium dialuminate 1. Dication 12+ is valence isoelectronic with elusive hex...

Interest in actinide–carbon bonds has persisted since actinide organometallics were first investigated for applications in isotope separation during the Manhattan Project. Transplutonium organometalli...

The homogeneous catalytic functionalization of methane is extremely challenging due to the relative nonpolarity and high C–H bond strength of this hydrocarbon. Here, using catalytic quantities (10 mol...