Nitrene insertion into the Ge<span class='icomoon'></span>Si bonds of masked bis(germylene)s is followed by nitrene addition to the Ge(II) centers to provide a bis(germaamidine) with GeN bonds bridged via a σ,π-conjugated amin...

A trigonal arylimido iron complex is reported which is found in an intermediate spin state. The iron bound imido unit is electronically flexible and acts as nucleophile, reductant, or H atom abstracto...