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A biomimetic model for the cysteine dioxygenase (CDO) was found to be also capable of selectively dioxygenating selenocysteamine, suggesting that the lack of reactivity found for the CDO in combinati....

Reduction of MnII precursors with bulky diamide ligands provided access to a complex with the longest known Mn–Mn bond and to a rare example of N2 activation at high-spin MnI centers. While some instr...

The synthesis and reactivity of a molybdenum carbonyl complex ligated by geometrically constrained phosphorus trisamide are reported. Reaction with potassium tert-butoxide or methanol triggers ligand...