We describe the synthesis of a phosphanyl-functionalized 1,3,5-triphosphabenzene that exhibits remarkably large indirect spin-spin coupling (432 Hz) between phosphorus-31 nuclei. The magnitude of this...

The homogeneous catalytic functionalization of methane is extremely challenging due to the relative nonpolarity and high C–H bond strength of this hydrocarbon. Here, using catalytic quantities (10 mol...

Despite their synthetic interest and potential attractive properties, the preparation of heteroleptic U(III) complexes containing monodentate ligands remains challenging. Here we report the synthesis...