AbstractThe rich chemistry of molecular framework materials enables precise control of physico-chemical properties through structural design of framework t

Covalent organic frameworks (COFs) with alkyl or triethylene glycol pore linings are probed with water-dissolved nitroxide radicals using CW EPR spectroscopy. Adsorption affinity, local polarity, and...

Abstract. Molecular diffusion in metal–organic frameworks (MOFs) is a key factor controlling their performance in catalysis, gas storage and separation, se

MIL−88 A is first described in 2004 and consists of a trinuclear iron cluster and fumaric acid as a linker, forming a porous structure. The flexibility of MIL−88 A upon uptake of water, with an expan...

The successful synthesis of metal–organic frameworks (MOFs) in high yield and purity critically depends on the details of the procedure. Therefore, the machine-readable as well as findable, accessible...

The rich chemistry of molecular framework materials allows for precise control of physicochemical properties by structural design of the framework topology and the underlying building blocks. In this contribution, we demonstrate for the first time the ...