AbstractThe rich chemistry of molecular framework materials enables precise control of physico-chemical properties through structural design of framework t

Covalent organic frameworks (COFs) with alkyl or triethylene glycol pore linings are probed with water-dissolved nitroxide radicals using CW EPR spectroscopy. Adsorption affinity, local polarity, and...

Abstract. Molecular diffusion in metal–organic frameworks (MOFs) is a key factor controlling their performance in catalysis, gas storage and separation, se

The successful synthesis of metal–organic frameworks (MOFs) in high yield and purity critically depends on the details of the procedure. Therefore, the machine-readable as well as findable, accessible...

The rich chemistry of molecular framework materials allows for precise control of physicochemical properties by structural design of the framework topology and the underlying building blocks. In this contribution, we demonstrate for the first time the ...

Soft porous crystals (SPCs) can undergo cooperative stimuli-responsive structural transitions that strongly impact the physical properties and pore structure of the crystal. Hysteretic behavior and c...

Single crystal diffraction analysis remains the gold standard for the three-dimensional atomic structure characterization of framework materials such as metal–organic frameworks, covalent organic fram...

Twisted bilayer metal-organic frameworks produce dodecagonal quasiperiodic moiré patterns with tunable length scales. Here the authors show that isoreticular ligand design enables control over aperiod...