Enzymes serve as highly efficient and selective biological catalysts, essential across diverse fields such as industry, medicine, and biotechnology, and are vital to green chemistry due to their effic...

Ultrasonic industrial applications require theoretical support and practical guidance from a comprehensive understanding of sonochemical reaction dynamics. The influence of acoustic factors (frequency...

Ionic liquids (ILs) offer unique properties for electrochemical applications, but their synthesis typically requires large volumes of solvents and costly reagents, limiting scalability and sustainabil...

In this study, a mechanochemical adaptation of the McMurry coupling reaction was developed to synthesize ethylenes using Zn/TiCl4/Et3N as reagents. Leveraging solvent-free ball-milling conditions, the...

NaTi2(PO4)3, a NASICON-type sodium titanium phosphate (NTP), is a promising candidate for sodium-ion energy storage due to its robust structural and electrochemical properties. This study explores the...

Understanding the degradation mechanisms of perfluoropolyether (PFPE) lubricants is critical for the reliability of Heat-Assisted Magnetic Recording (HAMR) systems. In this study, we conducted ReaxFF ...

In this study, we disclosed that calcium-based heavy Grignard reagents, prepared in situ through a mechanochemical method, reacted with gem-difluorostyrenes in the absence of transition-metal catalyst...

We present a direct mechanocatalytic approach for the Mizoroki–Heck coupling of aryl iodides with olefins using palladium milling balls as catalyst under elevated temperatures in a ball milling reacto...

A free-flowing, homogeneous and non-pyrophoric powder of Na/NaCl is prepared via planetary ball-milling. The mechanochemically micronised Na/NaCl serves as a highly activated source of sodium and was ...

Deep understanding of reaction kinetics in mechanochemical conditions is crucial to further advance this field of solid-state chemistry. However, a formidable challenge owing to the complexity of thes...

Hydrochloride (HCl) salts are among the most common solid forms of active pharmaceutical ingredients (APIs) because of their favorable physicochemical properties, including enhanced solubility and…

The presented work sets out to investigate the dehydrogenation behaviour of Ca(AlH4)2 + 2MCl (M = Li, Na) mixtures. In contrast to the by-product NaCl, which does not affect the decomposition of Ca(Al...

Amorphous-to-crystalline transformation is of profound importance in the crystallization of covalent organic frameworks (COFs), yet its potential through solid-state mechanochemistry remains largely u...

The formation of amide bonds is of major interest in organic chemistry. Several methodologies have emerged in mechanochemistry to promote this reaction by using coupling agents. Herein, the acylation ...

Aspirin's oral bioavailability is about 50%, but this can be significantly improved through nanocrystal formulation and polymorphic transformation. However, achieving homogeneous nanocrystals with opt...

Mechanochemistry has become a powerful and sustainable approach in synthetic chemistry, yet the fundamental principles governing energy transfer during milling remain poorly understood. In particular,...

Mechano-chemical activation is of rapidly growing interest for producing cementitious constituents from clays. The chemical reactivity of clay minerals is enhanced during intensive grinding, due to mechano-chemical...