In this proof-of-concept study, we show that polyfluorinated trityl radicals with the, to this date, highest fluorination grade can be accessed in quantitative yields in a straightforward manner start...

10 Jahre Förderung für Nachhaltigkeitsforschung

Chlorine is an essential feedstock for polymers and pharmaceuticals, with annual production exceeding 100 Mt. Nearly all Cl2 is obtained by chlor–alkali electrolysis, which consumes about 2.58 MWh of ...

Chlorine is an essential feedstock for polymers and pharmaceuticals, with annual production exceeding 100 Mt. Nearly all Cl2 is obtained by chlor–alkali electrolysis, which consumes about 2.58 MWh of ...

Lewis acids and their related weakly coordinating anions (WCAs) are central species in chemistry, and tuning their properties toward different purposes is still a challenging field of research. In thi...

Chlorine is essential for the production of plastics and pharmaceuticals but poses significant safety and environmental risks. Herein, processes are presented that substitute chlorine or reduce its d...

We report on the generation of F2B–As═BF, an arsinoborene (boranylidenearsane) with a genuine As═B double bond, where both the As and B atoms are two-coordinate. It was obtained from the reaction of A...

Herein, we present the first easy-to-access synthesis of the perfluorotrityl cation (15F+) with commercial GaCl3 and the further functionalization of the para-fluorine atoms of 15F+ via halodefluorin...