Abstract. Fused cyclopropanes are prominent motifs in bioactive molecules, yet their incorporation into densely functionalized frameworks remains a signifi

Fused cyclopropanes are prominent motifs in bio-active molecules, yet their incorporation into densely functionalized frameworks remains a significant synthetic challenge. Herein, we report a light-mediated dearomative cyclopropanation of ben-...

Nature has inspired chemists to develop photocatalytic processes that harness visible light, offering alternative reaction pathways beyond traditional thermal methods. Energy Transfer (EnT) is a part....

Three-dimensional heterocycles are crucial in medicinal chemistry, yet efficient methods for their preparation remain limited. We report a light-mediated [2 + 2] dearomatization strategy for simple an...

We present the first synthesis of bridged bicycles through the dearomatization of sterically and electronically unbiased aryl fragments. The visible-light promoted method occurs at room temperature a...

A family of heteroleptic Iridium(III) complexes, which can act as Energy Transfer (EnT) photocatalysts, has been prepared and tested in photochemical transformations. Our study explores ligand design...