Oxidatively induced reductive elimination (OIRE) is a powerful strategy for the formation of carbon–carbon bonds and has been widely employed in late transition metal catalysis. In contrast, early tra...

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A series of frustrated Lewis pair (FLP) stabilized arsenic compounds with formal oxidation numbers at As of +1, 0, and −1 are presented. A stable FLP-chelated complex of As2 was prepared which underg....

PhD Project - Sustainable Catalysis with Sb and Bi Pincer Complexes at The University of Manchester, listed on FindAPhD.com

In contrast to transition elements, s- and p-block metal compounds that coordinate carbon monoxide (CO) under near-ambient conditions are elusive. Here, we report an isolable, crystalline main-group m...

A biradical cyclic alkyl(amino)carbene-stabilised 9,10-diboraanthracene (DBA) activates small molecules such as hydrogen, phenyl azide or TEMPO (2,2,6,6-tetramethylpiperidin-1-oxyl) across its two bor...

Cleaving a benzene ring under mild conditions requires disrupting its aromaticity, which is a significant challenge in modern chemistry. Although the generation of cyclic products from cleaving benzen...

Unsymmetrical bis(anilido)xanthene ligands, decorated by a 2,4,6-tricyclohexylanilido substituent and a less bulky anilido group, are readily prepared in moderate yields from a 4,5-dibromo-substituted...

High-valent nickel species are implicated as intermediates in industrially relevant chemical transformations and in the catalytic cycles of metalloenzymes. Although a small number of tetravalent NiX4 ...