Very happy to share our latest pre-print. MHAT catalysis now combined with reductive radical-polar-crossover to unlock a new reactivity mode: hydrofunctionalisation with an electrophile (CO2). Excited to see this work come together and very proud of the team! #chemsky
doi.org/10.26434/che...
doi.org
Markovnikov Hydrocarboxylation Enabled by Reductive Cobalt Catalyzed Hydrogen-Atom-Transfer
Carbon dioxide is a promising feedstock for fine chemical synthesis, yet its inherent stability necessitates innovative catalytic strategies for its use as a reagent under mild conditions. A valuable ...