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Reposted by Ashish Parihar

Alan Goldman @catalyzer.bsky.social · 10/12/2025

Great work by all, led by @ashishchemist.bsky.social A very rare example where a new catalytic reaction reveals a very fundamental organometallic question (Why is reductive elimination - and the reverse oxidative addtn - kinetically so much more favorable for Os than the isoelectronic Ir complex?)

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Reposted by Ashish Parihar

Alan Goldman @catalyzer.bsky.social · 09/09/2025

Outstanding work by @ashishchemist.bsky.social and the team yields some promising catalysis and raises some extraordinarily fundamental organometallic questions!

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Reposted by Ashish Parihar

Goldman Group @goldmangroup.bsky.social · 09/09/2025

Check out this preprint from @goldmangroup.bsky.social on (Pybox)Os-catalyzed tail-to-tail homo/hetero coupling of α-olefins. Striking mechanistic differences from isoelectronic (Phebox)Ir shed light on fundamental steps of oxidative addition and reductive elimination. doi.org/10.26434/che...

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Reposted by Ashish Parihar

Goldman Group @goldmangroup.bsky.social · 13/03/2025

Check out this work from @goldmangroup.bsky.social in JACS @acsjacs.bsky.social telling an interesting story on bizarre selectivities for alkane dehydrogenation, H/D exchange and much more. Congrats to our very own Ashish @ashishchemist.bsky.social, Faraj, Tom and Alan @catalyzer.bsky.social

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Reposted by Ashish Parihar

Alan Goldman @catalyzer.bsky.social · 26/11/2024

Great work by @ashishchemist.bsky.social and Faraj Hasanayn (AUB) demonstrating an unprecedented mode of alkane C-H activation leading to alkane dehydrogenation, olefin hydrogenation, and H Isotope Exchange with bizarre selectivity.

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