Highly axial lanthanide complexes with strong magnetic anisotropy are attractive candidates for high-performance single-molecule magnets. Now dysprosium(III) and terbium(III) homoleptic bis(stannoledi...

The synthesis and characterization of novel mixed group 14/15 metallacycles incorporating a transition-metal is described. All of the presented compounds were obtained by reduction of an organometall...

Heterobimetallic Cu(I)–Rh(I) and Cu(I)–Ir(I) complexes are synthesized using a phosphine-substituted amidinate ligand via both stepwise and one-pot reactions. The Cu(I)–Ir(I) complex is further emplo...

A rare silicon(IV)-based azo compound featuring a Si─N═N─Si linkage was synthesized via the direct reaction of an organoazide with a silaiminyl–silylene precursor. This compound undergoes an unusual ...

The current study investigates the dynamic interactions of barium ions with a synthetic polymer, leading to the formation of intramolecularly folded single-chain nanoparticles (SCNPs), providing targe...

The syntheses of luminescent heterobimetallic ionic complexes based on the bis(phosphine)-functionalized β-diketiminate ligand [HC{(CH3)C}2{(o-[P(C6H5)2]2C6H4)N}2]− (PNac) are reported. This orthogona...

Recently, we discovered that silaiminyl-silylene, [LSi–Si(NDipp)L] (L = PhC(NtBu)2, Dipp = 2,6-diisopropylphenyl), can be converted from a mono-silylene to bis-silylene by using Lewis acids. This reve...

A novel phosphine−functionalized COT ligand and its inverse sandwich alkali metal complexes (Na, K, Rb, and Cs) were synthesized and structurally characterized. The polymeric architectures vary with ...

The coordination and functionalization of white phosphorus (P4) by transition metal and main group element compounds has led to a great variety of polyphosphides. However, larger polyphosphides of th....

Photochemical action plots are a powerful tool for investigating the wavelength-dependent efficiency of photochemical processes. Herein, we apply the photochemical action plot methodology developed b...