New insights into primary and secondary coordination sphere effects in Rh(I) dimers with NIR emission - published in @angewandtechemie.bsky.social
Huge thanks to @wengeroliver.bsky.social for exceptional mentorship and Giacomo Morselli for great collaboration
doi.org/10.1002/anie.6066376
doi.org
Controlling Near‐Infrared Fluorescence‐to‐Phosphorescence Ratios and Triplet Lifetimes in Rhodium(I) Dimers via Primary and Secondary Coordination Sphere Effects
RhI dimers with bridging aryl isocyanide and di-phosphine ligands show NIR-I or NIR-II fluorescence/phosphorescence, depending on the ligands and conformational rigidity at the Rh2 core. Rh-Rh intera...