Conspectus. Cell populations are inherently heterogeneous, and the molecular mechanisms that govern cellular plasticity and fate operate across broad spati

We synthesized diboron-embedded acenes and revealed that fusion mode governs electronic properties, whereas molecular symmetry dictates crystal packing. One C2v-symmetric isomer forms a uniform colum....

Lipid droplets provide low-polarity environments, yet their role in regulating supramolecular assembly pathways remains unclear. Here the authors demonstrate that triolein suppresses spontaneous nucle...

Metal-free ionic liquids that exhibit intense fluorescence in the visible region of over 500 nm in the fluid state remain scarce. Although small π-conjugated frameworks combining electron-donating and...

Coordination of a Lewis base switches an electron-accepting tricoordinate boron center into an electron-donating tetracoordinate one. An alkenyl-strapped diphenylthienylboryl π-system undergoes phosp....

Fibrous aggregates in triolein are constructed from a lipophilic donor–acceptor fluorophore bearing two phenylalanine-based diamide units. Spectroscopic analyses and fluorescence imaging revealed a k...

In this study a novel radical annulation reaction mode of Blatter and verdazyl radicals with arynes is demonstrated which offers access to antiaromatic and N-chiral triazines and tetrazinones. The ph...

Lipid droplets (LDs) are dynamic organelles essential to lipid metabolism and energy homeostasis, yet their compositional heterogeneity in living cells remains poorly understood. Here, we present Lipi...

Symmetrical and unsymmetrical incorporation of leucine-derived diamides with identical chirality into a benzothiadiazole-containing aryleneethynylene enables seeded control of three distinct chiral π-...

We report thieno-phospha-rhodamine (TPR) dyes as a novel class of near-infrared (NIR)-emissive fluorophores featuring an unsymmetric π-skeleton. TPR dyes exhibit emission maxima near 800 nm, large Sto...

A new class of donor–acceptor–acceptor-type fluorophores was developed, incorporating thieno[3,2-b]thiophene S,S-dioxide and dimesitylboryl units as dual acceptors, along with aminoaryl groups serving...