Very happy to see one of our first “big projects” out in
@angewandtechemie.bsky.social! 🎉 We translate a molecular dinickel motif onto mesoporous silica - retaining Ni–Ni cooperativity while gaining new chemoselectivity. Huge thanks to Jitpisut Poolwong & all coauthors!
doi.org/10.1002/anie...
doi.org
Defined Dinuclear Nickel Sites on Mesoporous Silica Translate Molecular Surface Mimics to Heterogeneous Catalysis
The cooperative reactivity characteristic of molecular dinuclear nickel complexes is transferred to mesoporous silica through a systematic immobilization strategy. The resulting material preserves th...
