Congratulations to Dorian Schutz and Wenwen Yang for this beautiful work in @orgchemfront.rsc.org Open Access !
doi.org/10.1039/D6QO...
doi.org
β- and Z-selective metal-free cyanation of ynamides: a direct approach to piperidines fused to arenes
Metal-free β- and Z-selective hydrocyanation of terminal ynamides using TMSCN and TBAF is described. The transformation proceeds with excellent regio- and stereoselectivity, delivering exclusively Z-c...
