This article reports on the isolation of a monomeric compound with a dianionic singly reduced bis(pyridylimino) isoindolide (BPI) ligand and elaborated discussions on the structure of reduced BPIs.

This work reports on the synthesis and characterization of alkali metal complexes of BPI and Me2BPI in reduced oxidation states. CV, EPR and XRD studies revealed detailed information about the unknow...

Frustrated Lewis Pairs (FLPs) as ambiphilic molecules are prone to activate small molecules and are in the focus of interest for many years. In this paper, we present the first ortho-phenylene bridge...

The unexpected reactivity and stability limits of phosphorus ylide-based aluminum- and gallium-carbon ambiphiles are described. While the previously published t-butyl-substituted compound (2-{AltBu2}...

A fully conjugated system built by alternate fusion of four benzene and three cyclopentadiene rings is a further rare example of an air- and moisture-stable carbon-centered hydrocarbon radical. It wa...