Abstract. The stoichiometric and catalytic hydrogenation of nitrous oxide mediated by gas/solid reactions of rhodium(II) pincer complexes [Rh(PNP-tBu)X]+ (

Stabilization of elusive aluminum(I) halides in the framework of an ambiphilic ligand is reported. The unique bonding situation at the trigonal-bipyramidal aluminum center is analyzed, and the coordi....

A systematic study is presented of the coordination chemistry of imidazolylphosphine-based PN(H)N pincer ligands at Rh, Ir, and Ru centers. The corresponding cationic complexes are active catalysts f....

Phosphaalkkenes are an underrepresented class of phosphorus-based ligands that hold great potential for the stabilisation of low-valent transition metal and main group fragments. We present the synthe...

The challenge of producing new environmentally friendly and fossil-free polyesters has strongly encouraged the development of bio-based alternatives such as poly(ethylene furanoate) (PEF) and polybuty...