Five-coordinate, square-pyramidal Fe(II) complexes adopting polar, non-centrosymmetric crystal structures exhibit exceptionally large easy-axis magnetic anisotropy. Ligand-driven distortions critical....

A new dysprosium-based single-molecule magnet works at higher temperatures than others in its class

A dysprosium amide–alkene complex shows soft magnetic hysteresis loops up to 100 kelvin, arising from the high charge density of the amide ligands and the structural role of the pendant alkene.

A dysprosium amide–alkene complex shows soft magnetic hysteresis loops up to 100 kelvin, arising from the high charge density of the amide ligands and the structural role of the pendant alkene.

Two heteroleptic octahedral Dy(iii) cis-aryloxide complexes, [Dy(OPh*)2(THF)3X] {HOPh* = 2,6-bis(diphenyl-methyl)-4-tert-butylphenol; X = Cl (1), Br (2)}, have been characterised by multi-frequency…

The threshold has been exceeded for only one year so far, but humanity is nearing the end of what many thought was a ‘safe zone’ as climate change worsens.