In fact we did not developed only one, but two complementary routes to free up space in #MOFs.
Acid washing or imidazole substitution happen in a single crystal to single crystal way, and can lead to porosity increase up to 50%.
#reticularchemistry
⬇️check it out⬇️
www.nature.com/articles/s41...
nature.com
Single-crystal to single-crystal editing of metal–organic frameworks via ligand removal - Nature Chemistry
The synthesis of metal–organic frameworks (MOFs) featuring wide mesopores or specific topologies often relies on the use of additional ligands known as centring structure-directing agents (cSDAs). Now...