Nickel complexes are able to undergo reactions with organohalides by a variety of fundamental steps, which can be either one-electron or two-electron in nature. Two electron processes are typically so...

Register now

We report the experimental and computational investigations of the reactions of aryl, heteroaryl, and vinyl triflates with a model nickel(0) complex. While the reactions of most (hetero)aryl and vinyl...

We are hiring a Postdoc! If you have PhD/PDRA experience in air sensitive, platinum group metal organometallics, are interested in using this expertise in single-crystal SMOM synthesis and reactivity,...

The development of broadly useful C-P cross-couplings of (hetero)aryl chlorides and HP(O)(R/OR)2 nucleophiles by use of nickel/DalPhos-based catalysts is described, along with findings from DFT studi....

Previous studies have hinted at the similarities of Mn(II) and Mg alkyl complexes. Advancing this field, here we present a comparative study of tetra(n-butyl) lithium manganate(II) and magnesiate. Com...