Reposted by @cathweetman.bsky.social
Our collaboration w/ @markstradiotto.bsky.social and team is now out in Chem. Eur. J. (@chemistryeurope.bsky.social)!
Mark's team used DalPhos ligands for Ni-cat. C-P couplings, which we supported with DFT calculations of reductive elimination.
doi.org/10.1002/chem...
@cathweetman.bsky.social
doi.org
Nickel‐Catalyzed P‐Arylation of HP(= O)(R/OR)2 Nucleophiles with (Hetero)Aryl Chlorides Enabled by DalPhos Ligation
The development of broadly useful C-P cross-couplings of (hetero)aryl chlorides and HP(O)(R/OR)2 nucleophiles by use of nickel/DalPhos-based catalysts is described, along with findings from DFT studi....
