Abstract. Bimetallic cooperative catalysis has overcome many of the established mechanistic limitations of monometallic reactivity in activating and transf

Protonation of a heterometallic silanide complex with an alcohol led to formation of a σ-silane complex. This reaction does not require a strong acid or weakly coordinating anion. Both metals of the h...

Although it marks a cornerstone of pnictenium ion [R2Pn]+ reactivity, the insertion of arsenium ions [R2As]+ into non-polar bonds remains highly challenging. Herein, a synthetic approach is developed...