Reposted by Sabyasachi Roy Chowdhury
Really happy with Bai's newest paper on unexpected bonding trends in #plutonium, #americium, and #curium coordination complexes.
Covalency of M–N Bonds in Isomorphous Lanthanide and Actinide 5-(2-Pyridyl)-1H-tetrazolate Complexes | JACS Au pubs.acs.org/doi/10.1021/...
pubs.acs.org
Covalency of M–N Bonds in Isomorphous Lanthanide and Actinide 5-(2-Pyridyl)-1H-tetrazolate Complexes
Experimental and computational analyses of [M(pdtz)3(H2O)3]·3.5H2O (M3+ = Pu3+–Cm3+, La3+–Nd3+, and Sm3+–Ho3+, pdtz– = 5-(2-pyridyl)-1H-tetrazolate) were conducted to understand potential differences ...