The chemical environment inside MOF pores controls how guest molecules are adsorbed, stored, and transformed within MOFs. We show that 1H and 19F nuclei that are present in the linker or introduced vi...

Atomic Layer Deposition (ALD) is a scalable, solvent-free synthesis technique that is routinely used for the deposition of thin films with sub-Angstrom precision. The coating of nonplanar substrates v...

Solid-state NMR can capture the inequivalence of differently shaped MOF pores. We show that the chemical shifts of reporting substituents that extend a defined distance into a MOF pore reflect the por...

Heterogeneous catalysts confer notable practical advantages for large-scale reactions, while homogeneous catalysts permit targeted performance optimization. A rapid and general method for the heteroge...

Heterogeneous catalysts confer notable practical advantages for large-scale reactions, while homogenous catalysts permit targeted performance optimization. A rapid and general method for the heterogen...

Thieme E-Books & E-Journals

Transition-metal-catalyzed cleavage of the Si–H bond in silanes to yield silyl radicals requires substantial amounts of energy, which are commonly supplied by photons. For Rh(II) porphyrins, efficient...

MOF catalysis is not a successor to either homogeneous or classical heterogeneous catalysis, but rather a distinct domain of catalysis with its own set of advantages and limitations. This concept art...