Selenium, a group 16 (chalcogen) element, can endow metal oxides with unique properties when replacing oxygen atoms from specific sites. Polyoxometalates (POMs), a class of anionic metal oxide cluster...

An understanding of proton transfer and migration at the surfaces of solid metal oxides and related molecular polyoxometalates (POMs) and metal alkoxides is crucial for the development of reactivity i...

In this first systematic investigation of mechanochemical polyoxometalate (POM) reduction, (TBA)3[PMo12O40] was reacted with n equiv of lithium metal (n = 1–24) to generate PMo12/n products which were...

Understanding how modification of molecular structures changes the thermochemistry of H atom uptake can provide design criteria for the formation of highly active catalysts for reductive transformatio...