Two novel P–N ligands, 1-[2-(diphenylphosphanyl)ethyl]-1H-benzo-1,2,3-triazole (1) and its N2-isomer (2), were synthesized. Reaction of 1 and 2 with [Ir(μ-Cl)(cod)]2 and [Rh(μ-Cl)(cod)]2 in a 2:1 mola...

En colaboración con el CSIC. Seguramente que lo primero que nos viene a la cabeza al escuchar la palabra catalizador es pensar en el tubo de escape del coche que se utiliza para reducir las emisiones....

The bimetallic Co(I)/Co(–I) complex [Co(CO)2(κ3-P,N,P-PNHP)][Co(CO)4] shows excellent activities in the methanolysis of hydrosilanes, reaching TOF values of ca. 50 000 h−1. This behavior can be ascri...

The bimetallic Co(I)/Co(–I) complex [Co(CO)2(κ3-P,N,P-PNHP)][Co(CO)4] (1) has shown excellent activities in the methanolysis of hydrosilanes, surpassing the related bimetallic Co(I)/Co(–I) complex [C...

This concept article examines the potential of Earth-abundant metal catalysts in the dehydrogenative coupling of hydrosilanes and alcohols, a key transformation for sustainable organosilicon synthesi...

The [2 + 2 + 2] cycloaddition of alkynes and nitriles is an efficient and atom-economic method for the synthesis of pyridines. However, most of the examples so far reported entail the use of diynes, w...