Low-valent aluminum chemistry continues to expand the boundaries of main-group reactivity, yet the selective generation and transfer of Al(II) fragments remain underexplored. Controlled Al(II) transfe...

Im Jahr 2025 waren aller guten Dinge der Hauptgruppenchemie drei: ein dreifach geladenes Triborattrianion, ein Molekül mit linearer Al3-Einheit, das dritte Erdalkalimetall, das Stickstoff bindet, ein ...

Low-valent cadmium compounds have remained largely unexplored as electron reservoirs, with no precedent for their use in reduction or bond activation chemistry. Here, we address this gap by integratin...