The chemistry of the classical uranium(III) complex [U(N″)3] (N″ = {N(SiMe3)2}−) is well-developed; however, there have been surprisingly few studies of its reactivity toward N-heterocycles. Here, we ...

Uranocene, [UIV(η8-C8H8)2], is the actinide equivalent to ferrocene. While ferrocene is readily oxidised to the ferrocenium cation, higher oxidation states of uranocene are unknown. Here we report the elusive uranocenium cation, [UV(η8-C8H8)2]+ , and ...

We report the synthesis and characterization of crystalline m-terphenylthiolate uranium complexes supported by the bulky ligand system, SAriPr6 (SAriPr6 = {SC6H3-2,6-(Tripp)2}; Tripp = 2,4,6-iPr-C6H2)...