An absolute photon upconversion efficiency of 8.2% is demonstrated using a liquid triplet fusion medium that behaves as solid on excitonic timescales. The findings may drive higher efficiencies in nan...

Chirality has recently emerged as a new means to profoundly impact the properties of organic semiconductors for spin-optoelectronic applications. Yet, a clear mechanistic understanding of chiral structure–property relationships remains absent to date, particularly for photon interconversion processes such as singlet exciton fission and triplet fusion. In this perspective, we highlight recent work that investigates chiral structures for these processes. We discuss the various ways in which chirality can impact such conversion processes and suggest ways to leverage it to improve photon management for both energy applications and quantum information science.

In 2023-24 tax from the PRRT was less than an quarter the amount raised by HECS/HELP debts repayments.

Singlet fission photovoltaics enable the extraction of two electron–hole pairs from each higher-energy photon while leveraging a mature technology such as crystalline silicon (c-Si) as the underlying cell. Significant steps have been made in the development of singlet fission silicon photovoltaics, but all examples reported to date use tetracene as the singlet fission material. Tetracene is photochemically unstable and therefore unsuitable for commercial applications. Here we demonstrate singlet fission-derived triplet exciton transfer to c-Si from photochemically stable dipyrrolonaphthyridinedione (DPND) derivatives, with a thin layer of tin oxide as the passivation layer. An overlayer of poly(3,4-ethylenedioxythiophene) polystyrenesulfonate (PEDOT:PSS) was found to improve interface passivation further. These observations demonstrate that singlet fission photovoltaic devices can be made using stable and commercially viable materials.

Singlet fission photovoltaics enable the extraction of two electron–hole pairs from each higher-energy photon while leveraging a mature technology such as crystalline silicon (c-Si) as the underlying ...

Photochemical upconversion has several potential applications in optoelectronics. However, there is yet to be demonstrated a rational approach to high efficiencies in nanoscale solid state devices. He...

A high-sensitivity, broadband, transient, full-Stokes spectroscopy setup is demonstrated, which can detect quickly varying small signals from chiral emitters.

The mechanism of covalent bonding has been debated for a century, with proponents variously championing kinetic or potential energy as the driver. While detailed calculations have revealed the bonding...

Top row from left: Mr Damon de Clercq; Dr Elena Gorenskaia; Ms Made Ganesh Darmayanti; Dr James Watson; Ms Jess Algar. Bottom row: Dr Wenchao Duan; Dr Tuan Sang Tran; Dr Saheli Biswas; Dr Ken Aldren

Endowing chirality onto solution-processable semiconductors unlocks new bounds for their spin and optoelectronic properties. This Review discusses the synthesis, properties, characterization methods, ...

Perovskite films have rapidly emerged as leading active materials in optoelectronic devices due to their strong optical absorption, high carrier mobility, and ease of fabrication. While proving to be ...

PhD Project - PhD studentship in Indoor Photovoltaic Devices and Materials Integration for IoT Applications at Newcastle University, listed on FindAPhD.com